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ChemInform Abstract: The Influence of Ligand Bite Angle on the Enantioselectivity of Copper( II)-Catalyzed Diels-Alder Reactions.

✍ Scribed by I. W. DAVIES; L. GERENA; L. CASTONGUAY; C. H. SENANAYAKE; R. D. LARSEN; T. R. VERHOEVEN; P. J. REIDER


Book ID
112040324
Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
27
Category
Article
ISSN
0931-7597

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A CLFSE/MM study on the role of ligand b
✍ Ian W. Davies; Robert J. Deeth; Robert D. Larsen; Paul J. Reider πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 283 KB

A single force-field has been developed for modeling bis(oxazoline) and pyridine-bis(oxazoline) copper(ll)complexes. Using this force field the role of ligand bite-angle on the enantioselectivity of Cu(ll)-catalyzed Diels-Alder was confirmed and for the first time, a direct comparison of the role of