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ChemInform Abstract: Copper(II)-Bisoxazoline-Catalyzed Asymmetric Diels—Alder Reactions of α-Thioacrylates.

✍ Scribed by Varinder K. Aggarwal; D. Elfyn Jones; Ana M. Martin-Castro

Publisher
John Wiley and Sons
Year
2001
Weight
37 KB
Volume
32
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Catalytic Asymmetric Diels—Alder Reactions of α-Thioacrylates for the Preparation of Norbornenone.
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Catalytic Asymmetric Diels-Alder Reactions of α-Thioacrylates for the Preparation of Norbornenone. -Cu(II)-catalyzed asymmetric Diels-Alder cycloaddition of α-thioacrylates (I) with excess cyclopentadiene using a bisoxazoline as chiral auxiliary provides the corresponding cycloadducts (III) in high