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ChemInform Abstract: The First Highly Enantioselective Rh-Catalyzed Enyne Cycloisomerization.

✍ Scribed by Ping Cao; Xumu Zhang


Publisher
John Wiley and Sons
Year
2001
Weight
33 KB
Volume
32
Category
Article
ISSN
0931-7597

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The First Highly Enantioselective Rh-Cat
✍ Ping Cao; Xumu Zhang πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 83 KB πŸ‘ 1 views

In the deprotonated form, trans-[Os IV (tpy)(Cl) 2 (NSC 6 H 3 Me 2 )], the angle Os1-N1-S1 (129.5(2)8) and bond Os1-N1 (1.890(3) ) are relatively unchanged while there are significant changes in the angle N1-S1-C41 (104.3(2)8), and the bonds N1-S1 (1.596(4) ), and S1-C41 (1.784(4) cf. with Os1-Cl1 (

The First Highly Enantioselective Rh-Cat
✍ Ping Cao; Xumu Zhang πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 83 KB

In the deprotonated form, trans-[Os IV (tpy)(Cl) 2 (NSC 6 H 3 Me 2 )], the angle Os1-N1-S1 (129.5(2)8) and bond Os1-N1 (1.890(3) ) are relatively unchanged while there are significant changes in the angle N1-S1-C41 (104.3(2)8), and the bonds N1-S1 (1.596(4) ), and S1-C41 (1.784(4) cf. with Os1-Cl1 (

Highly Enantioselective Cycloisomerizati
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The rising demand for chiral raw materials, intermediates, and active ingredients in pharmaceuticals, agrochemicals, food additives, and fragrances provides the impetus for rapid developments in chiral technology. [1] It remains a huge challenge for organic chemists to develop highly enantiose-lecti