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ChemInform Abstract: Rh-Catalyzed Enyne Cycloisomerization.

✍ Scribed by Ping Cao; Bin Wang; Xumu Zhang

Publisher
John Wiley and Sons
Year
2000
Weight
35 KB
Volume
31
Category
Article
ISSN
0931-7597

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The First Highly Enantioselective Rh-Cat
The First Highly Enantioselective Rh-Catalyzed Enyne Cycloisomerization
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In the deprotonated form, trans-[Os IV (tpy)(Cl) 2 (NSC 6 H 3 Me 2 )], the angle Os1-N1-S1 (129.5(2)8) and bond Os1-N1 (1.890(3) ) are relatively unchanged while there are significant changes in the angle N1-S1-C41 (104.3(2)8), and the bonds N1-S1 (1.596(4) ), and S1-C41 (1.784(4) cf. with Os1-Cl1 (

The First Highly Enantioselective Rh-Cat
The First Highly Enantioselective Rh-Catalyzed Enyne Cycloisomerization
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In the deprotonated form, trans-[Os IV (tpy)(Cl) 2 (NSC 6 H 3 Me 2 )], the angle Os1-N1-S1 (129.5(2)8) and bond Os1-N1 (1.890(3) ) are relatively unchanged while there are significant changes in the angle N1-S1-C41 (104.3(2)8), and the bonds N1-S1 (1.596(4) ), and S1-C41 (1.784(4) cf. with Os1-Cl1 (