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ChemInform Abstract: The First Example of Oxiranyllithium and Oxiranyl Grignard Reagent Having a Carbanion Destabilizing Group: Generation, Property, and Some Synthetic Uses.

โœ Scribed by T. SATOH; K. HORIGUCHI


Book ID
112027905
Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
27
Category
Article
ISSN
0931-7597

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Generation of oxiranyllithiums and oxira
โœ Tsuyoshi Satoh; Shigeko Kobayashi; Shino Nakanishi; Kyoko Horiguchi; Shiro Irisa ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 910 KB

The first generation of oxiranyllithiums and oxiranyl Grignard reagents having a carbanion-destabilizing group (alkyl group) was realized from sulfinyloxiranes via the ligand exchange reaction of sulfoxides with tert-butyllithium or ethylmagnesium chloridein THF at -80 to -100 \*C. The generated oxi