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The first example of oxiranyllithium and oxiranyl grignard reagent having a carbanion destabilizing group: Generation, property, and some synthetic uses

โœ Scribed by Tsuyoshi Satoh; Kyoto Horiguchi


Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
243 KB
Volume
36
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES


Generation of oxiranyllithiums and oxira
โœ Tsuyoshi Satoh; Shigeko Kobayashi; Shino Nakanishi; Kyoko Horiguchi; Shiro Irisa ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 910 KB

The first generation of oxiranyllithiums and oxiranyl Grignard reagents having a carbanion-destabilizing group (alkyl group) was realized from sulfinyloxiranes via the ligand exchange reaction of sulfoxides with tert-butyllithium or ethylmagnesium chloridein THF at -80 to -100 \*C. The generated oxi