ChemInform Abstract: The First Chiral Zirconium(IV) Catalyst for Highly Stereoselective Sulfoxidation.
β Scribed by Marcella Bonchio; Giulia Licini; Fulvio Di Furia; Silvia Mantovani; Giorgio Modena; William A. Nugent
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 34 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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Synthesis and Application of the First Chiral and Highly Lewis Acidic Silyl Cationic Catalyst. -Cationic silyl compounds containing a chiral dimethylbinaphthyl backbone are synthesized and used as highly active Lewis acid catalysts for (hetero) Diels-Alder reactions with modest enantioselectivity.
The First Enantioselective Aza-Diels-Alder Reactions of Imino Dienophiles on Use of a Chiral Zirconium Catalyst. -The first examples of catalytic, enantioselective DA reactions of imine dienophiles with Danishefsky's dienes are reported. The free hydroxyl group of the aldimines is crucial with resp