ChemInform Abstract: The Effect of the Carbon Ligand on the Reaction of Organozinc Reagents in the Synthesis of Substituted 2,5-Dihydrofurans: A Rare Example of an Uncatalyzed Allylic Substitution Reaction Involving Alkyl Zinc Halides.

The Effect of the Carbon Ligand on the R

The Effect of the Carbon Ligand on the Reaction of Organozinc Reagents in the Synthesis of Substituted 2,5-Dihydrofurans: A Rare Example of An Uncatalysed Allylic-Substitution Reaction Involving Alkyl Zinc Halides

✍ Mark Woods; Nuno Monteiro; Geneviève Balme 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 369 KB 👁 2 views

Organozinc halides derived from Grignard reagents behave differently in their reaction with ethyl (±)-(2RS,3SR)-tetrahydro-4-methylene-2-phenyl-3-(phenylsulfonyl)furan-3-carboxylate (3) according to the hybridisation of the carbon ligand. During the development of short multi-component reactions for