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ChemInform Abstract: The CuBr/Fe(0) Promoted Radical Addition of Methyl 2-Br-2-Cl- carboxylates to Olefins.

✍ Scribed by L. FORTI; F. GHELFI; M. L. LANCELLOTTI; U. M. PAGNONI

Book ID: 112035915
Publisher: John Wiley and Sons
Year: 2010
Weight: 30 KB
Volume: 27
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199633085

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The Fe0 Promoted Addition of CCl4 and CCl3Br to Olefins. -In continuation of the work towards the alkylation of alkenes, it is shown that the previously reported reagent iron filings in DMF also promotes the Kharasch addition of CCl4 or BrCCl3 to olefins such as (I) , (IV), and (VII) in good yields