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ChemInform Abstract: The Fe0 Promoted Addition of CCl4 and CCl3Br to Olefins.

✍ Scribed by F. BELLESIA; L. FORTI; F. GHELFI; U. M. PAGNONI

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

The Fe0 Promoted Addition of CCl4 and CCl3Br to Olefins.

-In continuation of the work towards the alkylation of alkenes, it is shown that the previously reported reagent iron filings in DMF also promotes the Kharasch addition of CCl4 or BrCCl3 to olefins such as (I) , (IV), and (VII) in good yields. Other forms of iron such as turnings or powder are less efficient. It is noteworthy that the reaction may be explosive if the ratio of iron powder: CCl4 exceeds 0.084 (mmol/ mmol).

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