Scheme 1. A cyclohexene synthesis featuring a post-cycloaddition reductive transposition. Scheme 2. The Diels-Alder and reductive transposition chemistry of a 1hydrazinodiene. Reaction conditions: a) diethylmaleate, Et 2 AlCl, 23 8C, 75 %; b) Pd 2 A C H T U N G T R E N N U N G (dba) 3 , Et 2 NH, THF
ChemInform Abstract: The Catalytic Asymmetric Diels—Alder Reactions and Post-Cycloaddition Reductive Transpositions of 1-Hydrazinodienes.
✍ Scribed by Hao Xie; Glenn M. Sammis; Eric M. Flamme; Christina M. Kraml; Erik J. Sorensen
- Publisher
- John Wiley and Sons
- Year
- 2012
- Weight
- 76 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0931-7597
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