A stereoselective chlorination of a methyl group and the preference of cleavage of nonactivated primary C-H bonds in one of the methyl groups with respect to a weaker tertiary C-H bond in the course of the biosynthesis of barbamide point to a surprising, new mechanism of "biohalogenation" (see schem
✦ LIBER ✦
ChemInform Abstract: The Biosynthesis of Barbamide — A Radical Pathway for “Biohalogenation”?
✍ Scribed by Jens Hartung
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 25 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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