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ChemInform Abstract: The 1,3-Diaminobenzene-Derived Aminophosphine Palladium Pincer Complex {C6H3 [NHP(piperidinyl)2]2Pd(Cl)} — A Highly Active Suzuki—Miyaura Catalyst with Excellent Functional Group Tolerance.

✍ Scribed by Jeanne L. Bolliger; Christian M. Frech

Publisher: John Wiley and Sons
Year: 2010
Weight: 90 KB
Volume: 41
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201037073

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✦ Synopsis

Abstract

The new protocol is an improvement over previously reported methods due to its significantly broadened applicability.

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The 1,3-Diaminobenzene-Derived Aminophos

The 1,3-Diaminobenzene-Derived Aminophosphine Palladium Pincer Complex {C6H3[NHP(piperidinyl)2]2Pd(Cl)} – A Highly Active Suzuki–Miyaura Catalyst with Excellent Functional Group Tolerance

✍ Jeanne L. Bolliger; Christian M. Frech 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 204 KB

## Abstract The rapidly prepared 1,3‐diaminobenzene‐derived aminophosphine pincer complex {C~6~H~3~[NHP(piperidinyl)~2~]~2~Pd(Cl)} (**1**) is an effective Suzuki catalyst with excellent functional group tolerance. Side‐product formations, such as homocoupling, debromation or protodeboration have on