Cesium Fluoride Catalyzed Trifluoromethylation of Esters, Aldehydes, and Ketones with (Trifluoromethyl)trimethylsilane. -The title reaction is successfully applied to carboxylic, sulfonic, sulfinic, and selenic esters, and also to aldehydes and ketones, among them substrates that have been reported
β¦ LIBER β¦
ChemInform Abstract: Tetrabutylammonium Fluoride (TBAF)-Catalyzed Addition of Substituted Trialkylsilylalkynes to Aldehydes, Ketones, and Trifluoromethyl Ketones.
β Scribed by Venkat Reddy Chintareddy; Kuldeep Wadhwa; John G. Verkade
- Publisher
- John Wiley and Sons
- Year
- 2011
- Weight
- 56 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
TBAF is found to be highly efficient for the title reaction providing a wide range of propargylic alcohols in good to high yields.
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