ChemInform Abstract: Catalytic Enantioselective Addition of Diethylzinc to Trifluoromethyl Ketones.
β Scribed by Kimberly Yearick; Christian Wolf
- Publisher
- John Wiley and Sons
- Year
- 2009
- Weight
- 46 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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π SIMILAR VOLUMES
1998 stereochemistry stereochemistry (general, optical resolution) O 0030 ## 48 -025 Catalytic Enantioselective Addition of Diethylzinc to (Hetero)Aromatic Aldehydes. -The title investigation is presented with a view to the importance of enantiomerically pure (hetero)aryl alcohols in organic synt
The asymmetric alkylation with diethylzinc of five heterocyclic aldehydes and benzaldehyde (for comparison) has been studied in the presence of two optically active amino alcohols: (S)-2-amino-1-butanol (AB) and (1S,2R)-N,Ndibutylnorephedrine (DBNE). A number of chiral (hetero)aromatic secondary alc