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ChemInform Abstract: Tertiary Amine-S2Cl2 Chemistry: Interception of Reaction Intermediates.

✍ Scribed by C. F. MARCOS; O. A. RAKITIN; C. W. REES; L. I. SOUVOROVA; T. TORROBA; A. J. P. WHITE; D. J. WILLIAMS

Book ID
101869123
Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
29
Category
Article
ISSN
0931-7597

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## Abstract Allylic carbonates and tertiary amine nucleophiles undergo palladium‐catalyzed formation of ammonium ylides which subsequently rearrange to amino acid derivatives or complex α‐amino ketones with unprecedented levels of diastereocontrol.