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ChemInform Abstract: tert-Butyldimethylsilyldihalomethyllithium as a Dihalomethylene Dianion Synthon. 1,3-Rearrangement and 1,4-Rearrangement of Silyl Group from Carbon to Oxide.

โœ Scribed by H. SHINOKUBO; K. MIURA; K. OSHIMA; K. UTIMOTO


Book ID
112030782
Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
27
Category
Article
ISSN
0931-7597

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tert-Butyldimethylsilyldichloromethyllit
โœ Hiroshi Shinokubo; Katsukiyo Miura; Koichiro Oshima; Kiitiro Utimoto ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 302 KB

One-pot syatksir of R~H(OS~~~~-~-BII~CC~~CH(OH)R~ by auccurive sdditim of two diffmt damphih haa ban ticvcd startinp from terMmtyldimcthylsiilyldidtl~yRithium. Trcammu 0faTHF sduth d the title cmbanbn with @+4&C,jH4Cm) Or n-BnCHO followed by aa addition of HhiPA and bamddd~ydc &ave the amqmdhg 1.3di