✦ LIBER ✦
tert-Butyldimethylsilyldichloromethyllithium as a dichloromethylene dianion synthon. 1,3-rearrangement of silyl group from carbon to oxide
✍ Scribed by Hiroshi Shinokubo; Katsukiyo Miura; Koichiro Oshima; Kiitiro Utimoto
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- French
- Weight
- 302 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
One-pot syatksir of R~H(OS~~~~-~-BII~CC~~CH(OH)R~ by auccurive sdditim of two diffmt damphih haa ban ticvcd startinp from terMmtyldimcthylsiilyldidtl~yRithium. Trcammu 0faTHF sduth d the title cmbanbn with @+4&C,jH4Cm) Or n-BnCHO followed by aa addition of HhiPA and bamddd~ydc &ave the amqmdhg 1.3did monosilyl ether in 83% 0145% yidd. mpectivdy.