ChemInform Abstract: TBAF-Mediated Reactions of 1,1-Dibromo-1-alkenes with Thiols and Amines and Regioselective Synthesis of 1,2-Heterodisubstituted Alkenes.
β Scribed by Hui Xu; Shaojin Gu; Wanzhi Chen; Dacheng Li; Jianmin Dou
- Publisher
- John Wiley and Sons
- Year
- 2011
- Weight
- 69 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0931-7597
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## Abstract The Hirao reduction of 1,1βdibromoβ1βalkenes with diisopropyl phosphite generates intermediate 1βalkenylbromides, which react with a second equivalent phosphite to afford desired 1βalkenylphoshonates.