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ChemInform Abstract: Synthetic Study on Top-Half (C14—C25) Fragment of Amphidinolide B, a 26-Membered Macrolide.

✍ Scribed by Katsuhide Ohi; Shigeru Nishiyama

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
30
Category
Article
ISSN
0931-7597

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Synthetic Studies Toward Potent Cytotoxic Agents Amphidinolides G and H: Synthesis of the Entire C 15 -C 26 Moiety of the Top Half. -The synthesis of segment (IX) utilizes stereoselective allylation of N-acyloxazolidines (I), a diastereoselective aldol condensation between aldehyde (IV) and chiral