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ChemInform Abstract: Synthetic Study of Marine Polycyclic Ethers: Total Synthesis of Hemibrevetoxin B

โœ Scribed by Tadashi Nakata


Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
30
Category
Article
ISSN
0931-7597

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Stereocontrolled Total Synthesis of Hemibrevetoxin B. -A linear approach to the total synthesis of title compound (I) is accomplished with high stereoselectivity in 56 steps and 0.75% overall yield from D-mannose. Key step in this synthesis is the intramolecular reaction of ฮณ-alkoxyallylstannanes wi

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## Abstract For Abstract see ChemInform Abstract in Full Text.