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ChemInform Abstract: Synthetic Studies on Vitamin D Analogues. Part 39. Synthesis of 1-Deoxyeldecalcitol, a Biologically Interesting Analogue of 1α,25-Dihydroxy-2β-(3-hydroxypropoxy)vitamin D3 (Eldecalcitol).

✍ Scribed by Hirotaka Sasaki; Kohei Eto; Keisuke Takahashi; Jun Ishihara; Susumi Hatakeyama; Noboru Kubodera

Publisher: John Wiley and Sons
Year: 2011
Weight: 33 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201143193

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✦ Synopsis

Abstract

The synthesis of 1‐deoxyeldecalcitol (IV) is realized employing Trost′s methodology involving a palladium‐catalyzed coupling between enyne (II) and bromoalkene (III) as key step.

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