ChemInform Abstract: Synthetic Methods. Part 3. Sulfated zirconia Catalyzed Thioacetalization of Carbonyl Compounds.
β Scribed by B. P. BANDGAR; S. P. KASTURE
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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Solvent-Free Thioacetalization of Carbonyl Compounds Catalyzed by Cu(OTf ) 2 -SiO 2 . -Copper(II) triflate on silica gel (activated at 120 β’ C at 1mm Hg for 6h) allows the solvent-free thioacetalization of aldehydes and ketones in an efficient manner.
General Synthetic Methods. Part 6. Chlorotrimethylsilane-Catalyzed Acylation of Alcohols. -The acylation of a variety of alcohols is effectively catalyzed by chlorotrimethylsilane. This reaction works well with primary, secondary, and allylic alcohols. However, elimination is observed with tertiary
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