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ChemInform Abstract: Synthetic Applications of Functionalized Silyl Anions: Aminosilyl Anions as Hydroxy Anion Equivalent.

โœ Scribed by K. TAMAO; A. KAWACHI; Y. TANAKA; H. OHTANI; Y. ITO

Book ID
112035593
Publisher
John Wiley and Sons
Year
2010
Weight
35 KB
Volume
27
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Behavior of Dioxola
ChemInform Abstract: Behavior of Dioxolanones as Chiral Acyl Anion Equivalents.
โœ R. A. AITKEN; A. W. THOMAS ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 35 KB ๐Ÿ‘ 2 views

Behavior of Dioxolanones as Chiral Acyl Anion Equivalents. -Deprotonation of 1,3-dioxolan-4-ones [cf. (I)] and following alkylation gives products (III). Their flash vacuum pyrolysis yields ketones (IV) (with concomitant loss of CO and acetone) showing (I) to be acyl anion equivalents. Conjugate ad