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ChemInform Abstract: Synthesis, Properties, and Structure of Ammonium 4-Aryl-5-cyano-2-oxo- 1,2,3,4-tetrahydropyridine-6-thiolates.

✍ Scribed by V. N. NESTEROV; S. G. KRUVOKOLYSKO; V. D. DYACHENKO; V. V. DOTSENKO; V. P. LITVINOV


Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
28
Category
Article
ISSN
0931-7597

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Ethylcrotonates in the Synthesis of 4,4-Disubstituted 3,5-Dicyano-6oxo-1,4,5,6-tetrahydropyridine-2-thiolates. -Michael addition of ethyl crotonate (I) to cyanothioacetamide (II) in the presence of N-methylmorpholine and subsequent in situ cyclization affords the title tetrahydropyridinethiolates as