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ChemInform Abstract: Synthesis of ω-Substituted Alkanethiols and (Bromomethyl)methylthiomalonates.

✍ Scribed by Michael J. Pfammatter; Vuk Siljegovic; Tamis Darbre; Reinhart Keese

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
32
Category
Article
ISSN
0931-7597

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Synthesis of ω-Substituted Alkanethiols
Synthesis of ω-Substituted Alkanethiols and (Bromomethyl)methylthiomalonates
✍ Michael J. Pfammatter; Vuk Siljegovic; Tamis Darbre; Reinhart Keese 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 German ⚖ 151 KB

Several multifunctional derivatives of methylthiomalonic acid ( 2-(thiocarboxy)acetic acid), i.e. 20a, b, 21, 22a, b, and 24, were prepared from thiols bearing a functionalized head group, i.e. from 9a, b, 12, and 16d, f (Schemes 4 and 5). The association constants of the two dithio podands 8b and 1