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ChemInform Abstract: Synthesis and Application of ω-Epoxyfunctionalized Alkoxysilanes

✍ Scribed by G. SPERVESLAGE; K. STOPPEK-LANGNER; J. GROBE


Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
29
Category
Article
ISSN
0931-7597

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Synthesis of α-Alkoxysilanes: Birch Reduction of 2-Trialkylsilylfurans. -Birch reduction of 2-silylfuran-3-carboxylic acids such as (I) results in diastereoselective formation of the trans products after diazomethane esterification and final catalytic hydrogenation. The silyl substituent of (IIIa)