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ChemInform Abstract: Synthesis of the Thiazole-Containing C11—C21-Block (IX) of a gem-Dimethylcyclopropane Derivative of Epothilones.

✍ Scribed by Natal'ya K. Selezneva; Fanuza A. Gimalova; Ruslan F. Valeev; Mansur S. Miftakhov

Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
41
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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ChemInform Abstract: Synthesis Toward Ep
ChemInform Abstract: Synthesis Toward Epothilone A: Coupling Reaction Between the Sulfone of C1—C10 and the Allylic Bromide of C11—C21.
✍ Hyo Won Lee; Yong Deog Hong; Ihl-Young Choi Lee 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 2 views

Synthesis Toward Epothilone A: Coupling Reaction Between the Sulfone of C 1 -C 10 and the Allylic Bromide of C 11 -C 21 . -The synthesis of macrolide (XII), a precursor of epothilone A, involving the coupling between allylic bromide (IX) and sulfone (X) as the key step is reported. -