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ChemInform Abstract: Synthesis of the ′Enediyne′ Antibiotic Esperamicin A1, and Novel Analogues for Tumor Targeting

✍ Scribed by G. ULIBARRI; H. AUDRAIN; W. NADLER; H. LHERMITTE; D. S. GRIERSON

Book ID
112039345
Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
27
Category
Article
ISSN
0931-7597

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✍ H. MASTALERZ; T. W. DOYLE; J. F. KADOW; D. M. VYAS 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 2 views

## Synthesis of a Hybrid Analogue of the Esperamicin and Dynemicin Cores. -The compound (VI) represents an enediyne analogue hybrid of the core structures of esperamicin and dynemicin. Key step in the sequence is the intramolecular Reissert-type reaction of the anion of the Z-1,3-diyn-2-ene (III)