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ChemInform Abstract: Synthesis of Symmetrical Bis-(2-chloro-1,3,2-benzodiazaphosphorinones). Hydrolysis and Fluorination of Selected Compounds.

✍ Scribed by Zhaofu Fei; Holger Thoennessen; Peter G. Jones; Reinhard Schmutzler


Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
30
Category
Article
ISSN
0931-7597

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The hydrolysis of 1,2-bis(5,6-benzo-1-methyl-2chloro-1,3,2-diazaphosphorin-4-on-3-yl)ethane (1) and its 1,3-propane derivative (2) with excess water led, without decomposition, to the formation of the bis-phosphoryl compounds 3 and 4. Reaction of 1 and 2 with bis(trimethylsiloxy)ethane formed the sy

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