The series of symmetrical bis-amides 3 was formed by the reaction of N-methylisatoic anhydride (1), with the diamines 2. Reaction of 3 with phosphorus trichloride led to the formation of the symmetrical bis-(1,3,2-benzodiazaphosphorinones) (4). 4 c, 4 d and 4 e were easily hydrolyzed in moist air, l
ChemInform Abstract: Synthesis of Symmetrical Bis-(2-chloro-1,3,2-benzodiazaphosphorinones). Hydrolysis and Fluorination of Selected Compounds.
β Scribed by Zhaofu Fei; Holger Thoennessen; Peter G. Jones; Reinhard Schmutzler
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 36 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
The hydrolysis of 1,2-bis(5,6-benzo-1-methyl-2chloro-1,3,2-diazaphosphorin-4-on-3-yl)ethane (1) and its 1,3-propane derivative (2) with excess water led, without decomposition, to the formation of the bis-phosphoryl compounds 3 and 4. Reaction of 1 and 2 with bis(trimethylsiloxy)ethane formed the sy
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