Alkyl-Tethered Bis-Phosphoryl Compounds with two 1,3,2-Benzodiazaphosphorinone Units; Oxidation, Complexation, and X-Ray Structure Analysis of Selected Compounds

Symmetrical Bis-Phosphorus Compounds and

Symmetrical Bis-Phosphorus Compounds and Macrocycles with two 1,3,2-Benzodiazaphosphorinone Units – Oxidation and X-Ray Structure Analysis of Selected Compounds

✍ Zhaofu Fei; Yingzi Lu; Matthias Freytag; Peter G. Jones; Reinhard Schmutzler 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 German ⚖ 149 KB

The hydrolysis of 1,2-bis(5,6-benzo-1-methyl-2chloro-1,3,2-diazaphosphorin-4-on-3-yl)ethane (1) and its 1,3-propane derivative (2) with excess water led, without decomposition, to the formation of the bis-phosphoryl compounds 3 and 4. Reaction of 1 and 2 with bis(trimethylsiloxy)ethane formed the sy