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ChemInform Abstract: Synthesis of Sucrose Analogues Modified at Position 4.

✍ Scribed by C. SIMIAND; H. DRIGUEZ

Book ID
112024494
Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
26
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES

Sucrose analogues modified at position 3
Sucrose analogues modified at position 3: chemoenzymatic synthesis and inhibition studies of dextransucrases
✍ CΓ©cile Simiand; Eric Samain; Olivier R. Martin; Hugues Driguez πŸ“‚ Article πŸ“… 1995 πŸ› Elsevier Science 🌐 English βš– 853 KB

Conditions for the large-scale (molar) oxidation of sucrose by Agrobacterium tumefaciens were improved, thus leading to homogeneous solutions of 3-ketosucrose in 40% yield. Treatment of this solution with hydroxylamine or methoxylamine afforded the corresponding oximes 3a and 3b (isolated as acetate