Sucrose analogues modified at position 3
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CΓ©cile Simiand; Eric Samain; Olivier R. Martin; Hugues Driguez
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Article
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1995
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Elsevier Science
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English
β 853 KB
Conditions for the large-scale (molar) oxidation of sucrose by Agrobacterium tumefaciens were improved, thus leading to homogeneous solutions of 3-ketosucrose in 40% yield. Treatment of this solution with hydroxylamine or methoxylamine afforded the corresponding oximes 3a and 3b (isolated as acetate