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ChemInform Abstract: Synthesis of Succinic Diesters via Reductive Coupling of α- Haloesters Using Samarium(II) Iodide and HMPA.

✍ Scribed by E. BALAUX; R. RUEL


Book ID
112032327
Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
27
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Reductive Opening o
✍ A. NIVLET; V. LE GUEN; L. DECHOUX; T. LE GALL; C. MIOSKOWSKI 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 36 KB

Reductive Opening of Cyclopropylogous α-Hydroxy Aldehydes and Ketones by Samarium(II) Iodide. -The regioselectivity of the title reaction is found to be strongly dependant on the substitution pattern of the substrate. In several cases, a tandem cyclopropyl opening-deoxygenation reaction leads to γ-