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ChemInform Abstract: Synthesis of Substituted (D)-Phenylalanine Derivatives by Regioselective Reduction of Enantiomerically Pure cis-2,3-Disubstituted Aziridines.

✍ Scribed by Jae-Won Chang; Jae Hyun Bae; Seong-Ho Shin; Chan Sun Park; Daeock Choi; Won Koo Lee

Publisher: John Wiley and Sons
Year: 2010
Weight: 29 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199910202

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✦ Synopsis

Synthesis of Substituted (D)-Phenylalanine Derivatives by Regioselective Reduction of Enantiomerically Pure cis-2,3-Disubstituted Aziridines.

-Intramolecular cyclization of chiral 2-amino-1,3-propanediol derivatives (I) and subsequent regioselective reduction of the resulting cis-2,3disubstituted aziridines (II) provides an efficient method for the preparation of a variety of substituted chiral amino alcohols (IV). -(CHANG, JAE-WON;

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