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ChemInform Abstract: Synthesis of Spiroketals Related to Griseusin A.

โœ Scribed by M. A. BRIMBLE; M. R. NAIRN


Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: A Novel Route to Mo
โœ R. ZEMRIBO; K. T. MEAD ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 34 KB ๐Ÿ‘ 1 views

A Novel Route to Monoanomeric Spiroketals. -The readily prepared spiroketal C2-acetal (XI) undergoes regioselective reaction with allylsilane. However, a monoanomeric spiroketal (XIII) is unexpectedly the major product. The sequence provides a model for the synthesis of the CD subunit of altohyrtin