ChemInform Abstract: Synthesis of Siloxanes. Part 24. Nucleophilic Substitution Reactions of 2-Functionalized 1,3-Dioxa-2,4,7-trisilacycloheptanes and 1,3-Dioxa- 2,4,8-trisilacyclooctanes
β Scribed by K. RUEHLMANN; S. JAEHNICHEN; U. SCHEIM; D. SCHELLER
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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Reaction of 2,2,4,5-Tetramethyl-1,3-dioxa-2-silacyclohexane with Diisobutyl Ester of Isobutylboronic Acid. -The trifluoroboranecatalyzed reaction of the title 1,3,2-dioxasilacyclohexane (I) with diisobutyl isobutylborate (II) results in a recyclization to afford the 1,3,2dioxaboracyclohexane (III).
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