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ChemInform Abstract: Synthesis of Selenium-Containing Bicyclic β-Lactams via Alkene Metathesis.

✍ Scribed by Dinesh R. Garud; Deepali D. Garud; Mamoru Koketsu


Publisher
John Wiley and Sons
Year
2009
Weight
41 KB
Volume
40
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Facile Synthesis of
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## Abstract Novel selenium‐containing bicyclic β‐lactams are synthesized by a stereoselective insertion of (but‐3‐enyl)seleno and propargylseleno moieties at the C(4) positions of azetidinones with subsequent ring‐closing enyne metathesis.

ChemInform Abstract: Alkene Metathesis i
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Alkene Metathesis in the Synthesis of Novel β-Lactams. -Monocyclic and bicyclic β-lactams like (VII) and (VIII) are prepared via alkene metathesis reactions using MOB as a catalyst. Compound (X) is obtained as minor side product during the synthesis of β-lactam (Vb). -(BARRETT,