ChemInform Abstract: Synthesis of Salinomycin.
β Scribed by P. J. KOCIENSKI; R. C. D. BROWN; A. POMMIER; M. PROCTER; B. SCHMIDT
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 28 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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Synthesis of (Β±)-Xanthocidin. -A total synthesis of the title compound (XII), which belongs to the cyclopentanone antibiotics, is presented with a view to the fact that this compound is biologically unavailable. Key step in this synthesis is a cationic cyclopentanellation which assembles the entire