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ChemInform Abstract: Synthesis of (.+-.)-Xanthocidin.

โœ Scribed by M. A. TIUS; D. J. DRAKE

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
28
Category
Article
ISSN
0931-7597

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โœฆ Synopsis

Synthesis of (ยฑ)-Xanthocidin. -A total synthesis of the title compound (XII), which belongs to the cyclopentanone antibiotics, is presented with a view to the fact that this compound is biologically unavailable. Key step in this synthesis is a cationic cyclopentanellation which assembles the entire carbon framework of (XII) (yield of (IX) given in g). -(TIUS, M. A.; DRAKE, D.

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