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ChemInform Abstract: Synthesis of Pulvinones via Tandem Dieckmann Condensation—Alkoxide β-Elimination.

✍ Scribed by Brice Nadal; Julien Rouleau; Helene Besnard; Pierre Thuery; Thierry Le Gall


Publisher
John Wiley and Sons
Year
2011
Weight
28 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

Reaction of acyloxyesters containing a trifluoroethoxy group (I) and (III) with LiHMDS proceeds via tandem Dieckmann condensation—alkoxide β‐elimination to give pulvinones (II) and (IV), respectively.


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