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ChemInform Abstract: Synthesis of gem-Difluoroalkenes via β-Fluoride Elimination of Organorhodium(I).

✍ Scribed by Tomoya Miura; Yoshiteru Ito; Masahiro Murakami

Publisher
John Wiley and Sons
Year
2009
Weight
31 KB
Volume
40
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.

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## Abstract Reaction of acyloxyesters containing a trifluoroethoxy group (I) and (III) with LiHMDS proceeds via tandem Dieckmann condensation—alkoxide β‐elimination to give pulvinones (II) and (IV), respectively.