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ChemInform Abstract: Synthesis of Pseudopterane Analogues by Intramolecular SE2′ Cyclization.

✍ Scribed by James A. Marshall; LuAnne M. McNulty; Dong Zou

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
30
Category
Article
ISSN
0931-7597

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✍ Anton S. Khartulyari; Martin E. Maier 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 181 KB

## Abstract A new strategy toward the important class of benzomorphans is described. The key bond formation is based on an intramolecular Buchwald–Hartwig enolate arylation reaction. Thus, alkylation of piperidones with __ortho__‐bromobenzyl bromides provides the necessary substrates. In the presen