ChemInform Abstract: Synthesis of New Enantiopure Aminodiols and Their Use as Ligands for the Addition of Diethylzinc to Benzaldehyde.
โ Scribed by Irena Philipova; Vladimir Dimitrov; Svetlana Simova
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 30 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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Synthesis of New Enantiopure ฮณ-Amino Alcohols: Their Use as Catalysts in the Alkylation of Benzaldehyde by Diethylzinc. -Seven ฮณ-amino alcohols are prepared by a convenient method based on 1,3-dipolar cycloaddition of the nitrone (I) to olefins. Among them the alcohols (VI) and (VIIa) are best cata
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Synthesis of Novel Chiral Diazole Derivative Ligands for the Enantioselective Addition of Diethylzinc to Benzaldehyde. -The high pressure promoted reaction of epoxides with several nitrogen heterocycles represents an access to a variety of chiral title ligands (13 examples). Each of these ligands i