ChemInform Abstract: Synthesis of New Derivatives of 5-Alkyl-6-(2,6-dihalobenzyl)-2-(methylsulfanyl)pyrimidin-4(3H)-one (VII) and the Features of Their Oxidation.
โ Scribed by I. A. Novakov; B. S. Orlinson; M. B. Navrotskii; A. S. Eremiichuk; L. L. Brunilina; E. A. Gordeeva; E. N. Gerasimov
- Publisher
- John Wiley and Sons
- Year
- 2011
- Weight
- 65 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0931-7597
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โฆ Synopsis
Abstract
Reaction of the title methylsulfanylpyridinones (VII) with hydrogen peroxide in acetic acid affords the corresponding uracils (VIII), instead of the expected sulfones.
๐ SIMILAR VOLUMES
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a โFull Textโ option. The original article is trackable v
## Abstract A series of new 2โsubstituted 3โ(4โchlorophenyl)โ5,8,9โtrimethylthieno[3โฒ,2โฒ:โ5,6]pyrido[4,3โ__d__]pyrimidinโ4(3__H__)โones **8** were synthesized __via__ an azaโ__Wittig__ reaction. Phosphoranylideneamino derivatives **6a** or **6b** reacted with 4โchlorophenyl isocyanate to give carbo