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ChemInform Abstract: Synthesis of Nectrisine and Related Compounds, and Their Biological Evaluation.

✍ Scribed by Yong Jip Kim; Akira Takatsuki; Naoto Kogoshi; Takeshi Kitahara

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
30
Category
Article
ISSN
0931-7597

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Novel Synthesis of Nectrisine and 4-epi-Nectrisine. -Nectrisine (VIII), a potent inhibitor of glycosidase, is prepared by a new route starting from D-(-)-diethyl tartrate. Key step is the reduction of a lactam precursor to the amino alcohol. Since all attempts to reduce lactam (IV) are unsuccessful