ChemInform Abstract: Synthesis of Multinary Rare-Earth Sulfides PrGdS3, NdGdS3, and SmEuGdS4, and Investigation of Their Thermoelectric Properties.
β Scribed by Michihiro Ohta; Toshihiro Kuzuya; Hideto Sasaki; Taku Kawasaki; Shinji Hirai
- Publisher
- John Wiley and Sons
- Year
- 2009
- Weight
- 17 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0931-7597
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Synthesis and Some Physical Properties of Rare-Earth Oxysulfostibnites. -Reaction of stoichiometric amounts of Ln 2 O 2 S (Ln: Eu, Dy, Ho, Yb) with Sb 2 S 3 at 1000-1050 β’ C in a sealed tube results in the formation of the new oxysulfostibnites LnSbOS 2 (I) and (LnO) 4 Sb 2 S 5 (II). Single crystal
## Abstract The title compounds are prepared by high temperature/high pressure reactions of mixtures of the elements in the molar ratio RE:B:S = 1:3:6 (3.5 GPa, 1673 K, 5 h).
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