Synthesis of methyl (d-glycopyranosyl az
β
ZoltΓ‘n GyΓΆrgydeΓ‘k; Joachim Thiem
π
Article
π
1995
π
Elsevier Science
π
English
β 430 KB
Sodium hypochlorite oxidation catalysed by 2,2,6,6,-tetramethylpiperidine 1-oxide (TEMPO) is shown to be a mild and efficient approach to the title uronates. In the gluco, galacto, allo, and 2-acetamido-2-deoxy-gluco series, the corresponding /3-or a-and /3-glycosyl azides could be smoothly oxidised