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ChemInform Abstract: Synthesis of Methyl (D-Glycopyranosyl Azide) Uronates.

✍ Scribed by Z. GYOERGYDEAK; J. THIEM


Book ID
112023466
Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
26
Category
Article
ISSN
0931-7597

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Synthesis of methyl (d-glycopyranosyl az
✍ ZoltΓ‘n GyΓΆrgydeΓ‘k; Joachim Thiem πŸ“‚ Article πŸ“… 1995 πŸ› Elsevier Science 🌐 English βš– 430 KB

Sodium hypochlorite oxidation catalysed by 2,2,6,6,-tetramethylpiperidine 1-oxide (TEMPO) is shown to be a mild and efficient approach to the title uronates. In the gluco, galacto, allo, and 2-acetamido-2-deoxy-gluco series, the corresponding /3-or a-and /3-glycosyl azides could be smoothly oxidised