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ChemInform Abstract: Synthesis of Methanes Having Four Different Carbon Substituents Utilizing Indium-Catalyzed Cleavage of Carbon—Pyrrolyl Bonds.

✍ Scribed by Teruhisa Tsuchimoto; Taku Ainoya; Kazuki Aoki; Tatsuya Wagatsuma; Eiji Shirakawa

Publisher: John Wiley and Sons
Year: 2009
Weight: 59 KB
Volume: 40
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200937100

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## Abstract A pyrrolyl group bound to an sp^3^ carbon atom in __gem__‐dipyrrolylalkanes was found to be successfully replaced by a certain range of carbon nucleophiles in the presence of an indium catalyst. The reaction can also be performed efficiently as a three‐component assembly of alkynes, pyr

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