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ChemInform Abstract: Iron-Catalyzed Synthesis of Glycine Derivatives via Carbon—Nitrogen Bond Cleavage Using Diazoacetate.

✍ Scribed by Yoichiro Kuninobu; Mitsumi Nishi; Kazuhiko Takai

Publisher
John Wiley and Sons
Year
2011
Weight
30 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

The reaction of tertiary amines (I) with ethyl diazoacetate in the presence of iron or manganese salts leads to N‐disubstituted glycine derivatives (III).

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## Abstract The application of the samarium diiodide fragmentation reaction to 5,5‐disubstituted oxopyrrolidines (I) leads to a regioselective carbon—nitrogen bond cleavage affording the 4,4‐disubstituted cleavage products (II).